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    A comparison between the safe amine based zinc dithiocarbamates with the unsafe zinc dimethyl dithiocarbamate (ZDMC) in the light of mechanical and aging resistance behavior, introduces the non carcinogenic rubber additives in the filled vulcanization of rubber.

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  • Zinc bis(dimethyldithiocarbamate) - Wikipedia

    The compound is a prototypical zinc dithiocarbamate, a broad class of coordination complexes with the formulae Zn(R 2 NCS 2) 2, where R can be widely varied. Such compounds are produced by first treating a secondary amine with carbon disulfide to give the dithiocarbamate (R 2 NCS 2 − ), which is then treated with zinc salts, as illustrated ...

  • Zinc dimethyldithiocarbamate 97% | Sigma-Aldrich

    Zinc dimethyldithiocarbamate 97% Synonym: Dimethyldithiocarbamic acid zinc salt, Ziram CAS Number 137-30-4. Linear Formula (CH 3) 2 NCSSZnSCSN(CH 3) 2. Molecular Weight 305.82 . Beilstein/REAXYS Number 3707008 . EC Number 205-288-3. MDL number MFCD00064797. PubChem Substance ID 24859808

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  • ZINC DIBENZYLDITHIOCARBAMATE (ZBEC)

    ZBEC has the best scorch resistance among zinc dithiocarbamate accelerators. Sulfur combines with nearly all elements. Sulfur forms ring and chain structures as it is the second only to carbon in exhibiting catenation.

  • Dithiocarbamate | CH2NS2- - PubChem

    Dithiocarbamate. Carbamodithioate. Dithiocarbamate anion. Carbamodithioic acid, ion(1-) Carbamic acid, dithio-, ion(1-)

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    Effect of zinc dithiocarbamates and thiazole-based accelerators on the vulcanization of natural rubber ... is observed in the zinc (N-benzyl piperazino) dithiocarbamate-accelerated system at 3:6 ...

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  • MSDS -008 Zinc Dimethyl Dithio Carbamate

    Chemical description: Zinc Dimethyl Dithio Carbamate CHEMICAL NAME CAS NO. CAS NO. EINECS NO. WT% Zinc Dimethyl Dithio Carbamate 137‐30‐4 205‐288‐3 >96 3. HAZARD IDENTIFICATION Classification of the substance or mixture : Classification according to EU directives 67/548/EEC or 1999/45/EC

  • Dimethyldithiocarbamate - an overview | ScienceDirect Topics

    Soylak and Yılmaz offered a simple and rapid technique for the separation and preconcentration of ziram (zinc dimethyldithiocarbamate). This method is known as vortex-assisted magnetic solid-phase extraction (VA-MSPE). They went on to use flame atomic absorption spectrometry (AAS) for the detection of zinc in ziram's complex structure.

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  • ZINC DIETHYLDITHIOCARBAMATE (ZDEC, EZ)

    Other vulcanizing agents include amine compounds for the cross-linking of fluorocarbon rubbers, metal oxides for chlorine-containing rubbers (notably zinc oxide for chloroprene rubber) and phenol-formaldehyde resins for the production of heat-resistant butyl rubber vulcanizates.

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  • Dithiocarbamate - Wikipedia

    A dithiocarbamate is a functional group in organic chemistry. It is the analog of a carbamate in which both oxygen atoms are replaced by sulfur atoms (when only 1 oxygen is replaced the result is thiocarbamate). A common example is sodium diethyldithiocarbamate. Dithiocarbamates and their derivatives are widely used in the vulcanization of rubber.

  • Ziram | C6H12N2S4Zn - PubChem

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  • Functionalized zinc(II) dithiocarbamate complexes: Synthesis ...

    The zinc atom is in a distorted octahedral environment formed by four sulfur atoms from two dithiocarbamate ligands acting as bidentate chelating ones, and two nitrogen atoms from the bipyridine molecule in a ZnS 4 N 2 system.

  • Zinc diethyldithiocarbamate 97% | Sigma-Aldrich

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  • The Mechanism of Zinc(II)-Dithiocarbamate-Accelerated ...

    These studies have revealed that, in a three-stage process, ZDMC exhibits a unique combination of catalytic activity: (1) It mediates the reaction between sulfur and rubber. This is achieved by incorporating sulfur atoms in the zinc-dithiocarbamate ring and inducing their insertion into an allylic C−H bond via an ene-like reaction.

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